A New Polyoxygenated Seco-cyclohexene Derivative fromArtabotrys pilosus
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چکیده
منابع مشابه
A new pyrrole derivative from the extracts of the fungus monascus pilosus-fermented rice.
A chemical study on the n-BuOH-soluble fraction of the 95% EtOH extract of red yeast rice fermented with the fungus Monascus pilosus BCRC 38093 (Eurotiaceae) has resulted in the isolation of one new natural pyrrole derivative, designated as monascuspyrrole (1) together with nine known compounds, 3β-hydroxystigmast-5-en-7-one (2), β-sitostenone (3), monascin (4), ankaflavin (5), N-trans-feruloyl...
متن کاملStructure of a fully protected seco-erythronolide B acid derivative.
(3S,4R,5S,6R,7R,9R,10S,11S,12S,13S,- 14R)-14-Benzyloxymethoxy-10,12-O-carbonyl-4-N- imidazolylcarbonyl-6,7-O-isopropylidene-3,5,7,9,11,- 13-hexamethylhexadec-1-ene-4,6,7,10,12,14-hexol, C38H56N2O9, Mr = 684.87, monoclinic, P2(1), a = 8.7302 (12), b = 15.597 (2), c = 14.463 (2) A, beta = 104.797 (10) degrees, V = 1904.1 (4) A3, Z = 2, Dx (198 K) = 1.19 g cm-3, mu = 0.7893 cm-1, Mo K alpha radiat...
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6,8a-deoxy derivatives of avermectins produced by a mutant strain of Streptomyces avermitilis K20571} derived by mutation from strain K2038 producing avermectins B l a and B2a selectively2). The parent strain K2038 carries two types of mutations, C-5 0-methylation (aveD) and the selective incorporation of branched-chain fatty acid into the avermectin molecule (X). The mutant strain K2057 has an...
متن کاملStructure Determination and Mechanism of Formation of a seco-Moreliane Derivative Supported by Computational Analysis.
Basic hydrolysis of a dichloromethane extract of Stevia lucida yielded (4R,5S,7R,9R,10R,11R)-7,9-dihydroxylongipin-2-en-1-one (1), which was oxidized and subjected to acidic conditions to generate the new seco-moreliane derivative 3. The structure of 3 was established based on NMR data interpretation and confirmed computationally. A plausible mechanism for the carbocationic rearrangement of the...
متن کاملA new polyoxygenated triterpene and two new aeginetic acid quinovosides from the roots of Rehmannia glutinosa.
A new minor polyoxygenated triterpene named glutinolic acid (1) and two new aeginetic acid quinovosides (2, 3) were isolated from the roots of Rehmannia glutinosa LIBOSCH. (Scrophulariaceae) cultivated in Gunwi-gun, Korea. The structures of these compounds were established as 3α,19α,20β,24,30-pentahydroxyurs-12-en-28-oic acid (1, glutinolic acid), aeginetic acid 5-O-β-D-quinovoside (2) and aegi...
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ژورنال
عنوان ژورنال: Chinese Journal of Organic Chemistry
سال: 2015
ISSN: 0253-2786
DOI: 10.6023/cjoc201505007